Just to confirm on the image that you have provided:
Yes, pins 2 and 3 indicate your primary pins of the transformer. I don’t see the NC pins of 1 and 4 in this image, but as long as they are on the primary side then they should have nothing connected here, you should be fine.
Yes, pins 6 and 8 along with 5 and 7 are your secondary outputs. You can connect each respective positive and negative terminals to your load in parallel to increase current capacity.
Let me know if there are any other specific questions, but it seems you already had the right ideas here.